[Co(HGPBzIT)Cl] | 955155-84-7

• 英文名称: [Co(HGPBzIT)Cl]
• 英文别名: [Co(1-acetylpyridinium chloride-4-benzoyl thiosemicarbazide((-1H))Cl]
• CAS: 955155-84-7
• 化学式: C₁₅H₁₄ClCoN₄O₂S*Cl
• 分子量: 444.267
• InChiKey: BQBNOHRKZVDZFJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 1-acetylpyridinium chloride-4-benzoyl thiosemicarbazide 以 乙醇 为溶剂， 生成 [Co(HGPBzIT)Cl]
  参考文献：
  名称：

  Synthesis, thermal and spectral studies of first-row transition metal complexes with girard P reagent-based ligand

  摘要：

  A new series of first-row transition metal complexes with 1-acetylpyridinium chloride-4-benzoyl thiosemicarbazide (H(2)GPBzIT) have been prepared and characterized by elemental analysis, spectroscopic and magnetic measurements. The proton-ligand ionization constants were determined potentiometrically using Irving-Rossotti technique. The stability constants of complexes were also calculated and were found in agreement with the seq uence of stability constants of Irving and Williams. Thermal stability and degradation kinetics have been measured using thermogravimetric analyzer. Kinetic parameters were obtained for each stage of thermal degradation of complexes using Coats-Redfem method. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.11.016