[(TXPB)Rh(μ-CO)2Fe(CO)Cp] | 917507-57-4

• 英文名称: [(TXPB)Rh(μ-CO)2Fe(CO)Cp]
• CAS: 917507-57-4
• 化学式: C₅₅H₅₃BFeO₃PRhS
• 分子量: 994.627
• InChiKey: VITCJDNYBBVQFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium cyclopentadienyldicarbonyliron(0) 、 [Rh(μ-Cl)(CO)(TXPB)] 以 甲苯 为溶剂， 以69%的产率得到[(TXPB)Rh(μ-CO)2Fe(CO)Cp]
  参考文献：
  名称：

  Synthesis of a Heterobimetallic Rhodium−Iron Complex Containing an η³-Interaction between Rhodium and the B−C_ipso−C_ortho Unit of a Triarylborane

  摘要：

  Reaction of [{RhCl(CO)(2)}(2)] with a phosphine/thioether/borane ligand (TXPB) gave [Rh(mu-Cl)(CO)(TXPB)] (1), a rare example of a complex containing a M-Cl-BR3 bridging interaction. Reaction of 1 with K[ CpFe( CO) 2] gave [(TXPB)Rh(mu-CO)(2)Fe(CO)Cp] ( 2), which contains an unprecedented eta(3)-interaction between rhodium and the B-C-ipso-C-ortho unit of a triarylborane. DFT calculations suggest a bonding description intermediate between that expected for an isolated borane/alkene complex and a fully delocalized allyl-like complex.

  DOI：

  10.1021/om060903m