| 207740-62-3

• CAS: 207740-62-3
• 化学式: C₂₄H₃₂F₆O₇S₂Ti
• 分子量: 658.516
• InChiKey: QLRUWEVIZJEGQX-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  (pentamethylcyclopentadienyl)Ti(OC6H3-2,6-i-Pr2)(Cl)2 、 silver trifluoromethanesulfonate 以 not given 为溶剂， 以59%的产率得到
  参考文献：
  名称：

  Synthesis of Various Nonbridged Titanium(IV) Cyclopentadienyl−Aryloxy Complexes of the Type CpTi(OAr)X₂ and Their Use in the Catalysis of Alkene Polymerization. Important Roles of Substituents on both Aryloxy and Cyclopentadienyl Groups

  摘要：

  Various titanium complexes of the type Cp'Ti(OAr)Cl-2 (Cp' = cyclopentadienyl; OAr = aryloxy) could be prepared in high yields from Cp'TiCl3. These complexes show remarkable catalytic activities for alkene polymerization with MAO or (AlBu3)-Bu-i-Ph3CB(C6F5)(4): (C-5-Me-5)Ti(O-2,6-(Pr2C6H3)-Pr-i)X-2 (X = Cl (2b), Me (8b), CF3-SO3 (9b)) showed the highest activities. The bond angle Ti-O-C (phenyl group) in 2b (173.0 degrees) is significantly different from those for other complexes (162.3-163.1 degrees).

  DOI：

  10.1021/om980106r