tetraphenylphosphonium trans-aquatetrabromo(carbonyl)osmate(III) | 176373-71-0

• 英文名称: tetraphenylphosphonium trans-aquatetrabromo(carbonyl)osmate(III)
• CAS: 176373-71-0
• 化学式: CH₂Br₄O₂Os*C₂₄H₂₀P
• 分子量: 895.238
• InChiKey: LXQCCXXWJIMMHV-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  、 Tetraphenylphosphonium hydrogen sulfate 以 水 为溶剂， 生成 tetraphenylphosphonium trans-aquatetrabromo(carbonyl)osmate(III)
  参考文献：
  名称：

  Tetraphenylphosphonium trans-Aquatetrabromo(carbonyl)osmate(III), trans-[(C6H5)4P][OsBr4(CO)(H2O)]

  摘要：

  The X-ray structure determination of tetraphenylphosphonium trans-aquatetrabromo(carbonyl)osmate(III) trans-[(C6H5)(4)P][OsBr4(CO)(H2O)], at 293 K has revealed slightly distorted octahedral coordination of the osmium(III) atom, with H2O trans to the almost linear carbonyl group. The distances are 1.795 (10) for Os-C, 2.181 (6) for Os-Ow and 1.164 (9) Angstrom for C--O; among the Os-Br bond lengths two are shorter [2.4692 (8) and 2.4753 (10) Angstrom] and two are longer [2.5042 (8) and 2.5072 (8) Angstrom]. Centrosymmetric dimers of the complex anions are formed by intermolecular hydrogen bonding between the coordinated water molecule and the two Br ligands that form longer bonds to the central atom.

  DOI：

  10.1107/s0108270195014259