| 254991-96-3

• CAS: 254991-96-3
• 化学式: BF₄*C₂H₃N*C₇H₁₈S₃Si*Cu
• 分子量: 417.907
• InChiKey: KMPFYVFYGIDMIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 Methyltris[(methylthio)methyl]silane 以 乙腈 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  One-Dimensional Copper(I) Coordination Polymers Based on a Tridentate Thioether Ligand

  摘要：

  The one-dimensional copper(I) coordination polymers Cu-3{MeSi(CH2SMe)(3)}(2)X-3 (X = Cl, Br) and [{MeSi(CH2SMe)(3)}Cu(NCMe)]Y (Y = OSO2CF3, BF4, PF6) were readily obtained in very good to excellent yields (80-95%) by reacting CuX or [Cu(NCMe)(4)]Y, respectively, with the tridentate thioether ligand MeSi(CH2SMe)(3) in acetonitrile. The new complexes were characterized by a combination of analytical and spectroscopic techniques, including electrospray ionization mass spectrometry and, for the bromo and hexafluorophosphate derivatives, single-crystal X-ray diffraction. Both complexes exhibit one-dimensional chain structures with approximately tetrahedral copper centers and bridging unibentate/bidentate thioether ligands.

  DOI：

  10.1021/ic990642r