| 482309-75-1

• CAS: 482309-75-1
• 化学式: C₂₆H₁₉NO₃STl*Na
• 分子量: 652.881
• InChiKey: KTKCRPIKNORFNN-BWUXSGITSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 氯化二苯基铊 在 NaOH 作用下， 以 甲醇 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  COORDINATION BEHAVIOUR OF 2-(1-CARBOXYL-2-HYDROXYPHENYL)BENZOTHIAZOLINE

  摘要：

  Reaction of 3-formylsalicylic acid with 2-aminobenzenethiol yielded 2-(1-carboxyl-2-hydroxyphenyl)benzothiazoline, H(2)chpbzn, rather than the corresponding Schiff base, 2-(2-mercaptophenyl) (3'-carboxy)salicylaldimine, H(3)mpcsalim. The reaction of H(2)chpbzn with (pi-C5H5)2TiCl(2), (pi-C5H5)(2)ZrCl2, CrCl3.6H(2)O, FeCl3 (anhydrous), VOSO4, VOCl3, Ni(OAc)(2).4H(2)O, Na2PdCl4, Me2TlCl, Ph2TlCl, BiCl3 and SbCl3, under varied reaction conditions, afforded the corresponding Schiff base complexes of the metal ions. For all of the complexes, except those of bismuth and antimony, the dianion of the Schiff base acts as a tridentate NSO donor ligand, while in the bismuth and antimony complexes the neutral benzothiazoline functions as a monodentate N donor ligand. Reactions of [(Hmpesalim)Ti(pi-C5H5)Cl], isolated in this study, with Me3SiE (where E stands for SMe, NMe2, N-3 and C=C Ph) have also been studied leading to the synthesis of many new organotitanium(IV) compounds. The prepared new compounds were characterized by elemental analyses, magnetic susceptibilities, molar conductance values, molecular weights and spectroscopic (UV-Vis, IR and H-1 NMR) data.

  DOI：

  10.1081/sim-120014857