| 934165-48-7

• CAS: 934165-48-7
• 化学式: C₁₈H₂₀Cl₂N₂Pt
• 分子量: 530.356
• InChiKey: IYXWTQLWMLCOCQ-UPPOFDQHSA-L

反应信息

• 作为产物：
  描述：

  potassium trichloro(ethylene)platinate(II) 、 glyoxalbis(2,6-dimethylphenylimine) 以 甲醇 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Synthesis and Structural Characterization of a Fluorinated α-Diimine Platinum(II) Complex

  摘要：

  The preparation of an electron-deficient (N-N)PtCl2 complex in which the diimine C is substituted by CF3 is described. Thus, reactions between the diimine ligand 1 (R = CF3, R' = 2,6-dimethylphenyl) and PtCl2 (thermal reaction) or KPtCl3(C2H4) (photochemically activated) furnishes the corresponding (N-N)PtCl2 complex 2. The ligand 1 and its Pt complexes 2, as well as related (N-N)PtCl2 complexes 3 (R = CO2CD3, R' = 2,6-dimethylphenyl; a methanolysis product) and 4 (R = H, R' = 2,6-dimethylphenyl) have been characterized by X-ray crystallography.

  DOI：

  10.1021/om060897u