| 94792-50-4

• CAS: 94792-50-4
• 化学式: C₂₈H₃₂ClIrSi
• 分子量: 624.321
• InChiKey: LNZDXIVNGXNFRD-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 三苯基硅烷 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Stereoselective Hydrosilylation of Terminal Alkynes Catalyzed by [Cp*IrCl₂]₂:  A Computational and Experimental Study

  摘要：

  The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl2](2) to afford selectively the beta-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed.

  DOI：

  10.1021/om0609158