(1,4,7,10,13,16-hexaoxacyclooctadecane)sodium tetrachlorogallate | 1105695-37-1

• 英文名称: (1,4,7,10,13,16-hexaoxacyclooctadecane)sodium tetrachlorogallate
• 英文别名: (1,4,7,10,13,16-hexaoxacyclooctadecane)sodium tetrachlorogallate [Na(CH2CH2O)6][GaCl4], cubic
• CAS: 1105695-37-1
• 化学式: C₁₂H₂₄NaO₆*Cl₄Ga
• 分子量: 498.844
• InChiKey: NWUPNROGXHLDKD-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  18-冠醚-6 、 氯化镓 、 sodium thiocyanide 以 甲醇 、 乙醇 为溶剂， 以15.8%的产率得到(1,4,7,10,13,16-hexaoxacyclooctadecane)sodium tetrachlorogallate
  参考文献：
  名称：

  Aggregates of the [GaCl4]− anion and the [Ga(H2O)3(NCS)3] complex with 18C6

  摘要：

  The complex formation in the system GaCl3-ROH-MNCS-18K6 is considered (ROH = MeOH, EtOH; M = Na, K; 18C6 is 1,4,7,10,13,16-hexaoxocyclooctadecane). Two modifications of [Na(18C6)][GaCl4], namely, aggregates [Na(18C6)][GaCl4](MeOH)(0.9)(EtOH)(1.1) and [Ga(H2O)(3)(NCS)(3)] center dot 18C6, are synthesized and identified. The Ga-71 NMR (solutions) and X-ray diffraction studies showed that the compositions and structures of the title compounds are determined by the ratio of the competing acido ligands (Cl- and NCS-) in the reaction solution.

  DOI：

  10.1134/s1070328407100041