(η(5)-C7H9)RuCl(dppe) | 207388-74-7

• 英文名称: (η(5)-C7H9)RuCl(dppe)
• CAS: 207388-74-7
• 化学式: C₃₃H₃₃ClP₂Ru
• 分子量: 628.096
• InChiKey: YEYIHAAGHHDMBJ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (η5-cycloheptadienyl)chloro-bis(triphenylphosphino)ruthenium 、 1,2-双(二苯基膦)乙烷 以 甲苯 为溶剂， 生成 (η(5)-C7H9)RuCl(dppe)
  参考文献：
  名称：

  The reaction between [(η5-C7H9)RuCl(H)(PPh3)2] and dihydrogen

  摘要：

  [(eta(5)-C7H9)RuCl(PPh3)(2)] has been shown to react with hydrogen to give [(eta(3)-C7H11)RuCl(PPh3)(2)] initially, and then [RuCl(HXPPh3)(3)], [Ru2H4Cl2(PPh(3)4)], and unidentified compound(s). This is a rare example of the hydrogenation of a coordinated ligand, where the ligand remains coordinated to the metal. It is suggested that the reverse reaction, involving the conversion of [(eta(3)-C7H11)RuCl(PPh3)(2)] to [(eta(5)-C7H9)RuCl(PPh3)(2)] is a rare example of the loss of dihydrogen from a coordinated ligand. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00428-2