[η5-C5H4CH2C3HN2(CH3)2]Co[η4-(Ph4C)] | 1105686-96-1

• 英文名称: [η5-C5H4CH2C3HN2(CH3)2]Co[η4-(Ph4C)]
• CAS: 1105686-96-1
• 化学式: C₃₉H₃₃CoN₂
• 分子量: 588.698
• InChiKey: PMFSAPJYSAGIJY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 [η5-C5H4CH2N(CH3)3I]Co[η4-(Ph4C)] 在 K₂CO₃ 作用下， 以 乙腈 为溶剂， 以45%的产率得到[η5-C5H4CH2C3HN2(CH3)2]Co[η4-(Ph4C)]
  参考文献：
  名称：

  Synthesis and Characterization of Novel Pyrazole‐Based Ligands of [η⁵‐Cyclopentadiene][η⁴‐Tetraphenylcyclobutadiene]Cobalt

  摘要：

  (eta(5)-N,N-dimethylaminomethylcyclopentadienyl)(eta(4)-tetraphenylcyclobutadiene) cobalt was prepared by the Mannich reaction of the metallocene (eta(5)-Cp)Co(eta(4)-Ph4C4) with tetramethylmethylenediamine and phosphoric acid. The methyl iodide salt of this compound was reacted with 3,5-dimethylpyrazole and 3-methyl-5-trifluoromethylpyrazole to prepare the pyrazole derived metallocenes, [eta(5)-(C5H4CH2)-3,5-(CH3)(2)(C3HN2)]CO[eta(4)-(Ph4C4)] (1) and [eta(5)-(C5H4CH2)-3-CH3-5-CF3(C4H2N)]Co[eta(4)-(Ph4C4)] (2). Compounds 1 and 2 were structurally characterized.

  DOI：

  10.1080/15533170701675139