[(C4H2N(2-CH2NH-t-Bu)(5-CH2NMe2))Al(SCHNPh)2] | 1202460-31-8

• 英文名称: [(C4H2N(2-CH2NH-t-Bu)(5-CH2NMe2))Al(SCHNPh)2]
• CAS: 1202460-31-8
• 化学式: C₂₆H₃₄AlN₅S₂
• 分子量: 507.703
• InChiKey: JQHIZBHZDMWEJL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(C4H2N(2-CH2NH-t-Bu)(5-CH2NMe2))AlH2] 、 硫代异氰酸苯酯 以 二氯甲烷 为溶剂， 以57.1%的产率得到[(C4H2N(2-CH2NH-t-Bu)(5-CH2NMe2))Al(SCHNPh)2]
  参考文献：
  名称：

  A New Type of Asymmetric Tridentate Pyrrolyl-Linked Pincer Ligand and Its Aluminum Dihydride Complexes

  摘要：

  The new pyrrolyl-linked pincer-type ligand, [C4H2NH(2-(CH2NHBu)-Bu-t)(5-CH2NMe2)] (1), that has been employed conveniently in high yield by treatment of (2-t-butylaminomethyl)pyrrole with 1 equiv of formaldehyde and dimethyl-amine hydrochloride each in diethylether and its corresponding aluminum derivative, [C4H2N(2-(CH2NHBu)-Bu-t)-(5-CH2NMe2)]AlH2 (2), that has been generated from Me3N center dot AlH3 using diethylether as a solvent are described. Furthermore, reactions of 2 with 2 equiv of either 1,3-diphenylpropane-1,3-dione in diethylether or phenyl thioisocyanate in dichloromethane interestingly formed [C4H2N(2-(CH2NHBu)-Bu-t)(5-CH2NMe2)]Al(PhCOCHCOPh)(2) (3) and [C4H2N(2-(CH2NHBu)-Bu-t)(5-CH2NMe2)]Al(SCHNPh)(2) (4), respectively, following deprotonation or hydroalumination reaction kinetics under a dry nitrogen environment. All of the compounds have been subjected to the X-ray diffraction technique in the solid state as well as characterized by NMR spectra.

  DOI：

  10.1021/ic9016189