[closo-1,2-Me2-3,3-(PPh3)2-3-H-3,1,2-RhC2B9H9] | 89509-53-5

• 英文名称: [closo-1,2-Me2-3,3-(PPh3)2-3-H-3,1,2-RhC2B9H9]
• CAS: 89509-53-5
• 化学式: C₄₀H₄₆B₉P₂Rh
• 分子量: 788.957
• InChiKey: FWXBRSJRWHFBCC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (η(3)-C8H13)Rh(η-7,8-Me2-7,8-C2B9H9) 、 三苯基膦 以 二氯甲烷 为溶剂， 以43%的产率得到[closo-1,2-Me2-3,3-(PPh3)2-3-H-3,1,2-RhC2B9H9]
  参考文献：
  名称：

  Synthesis, Characterization and Reactivity of [exo-nido-Rh(PPh₃)₂(η⁵-C₂B₉H₁₀Me₂)]

  摘要：

  In this work, the reaction of the 16-electron species [Rh(eta(3)-C8H13)(eta(5)-C(2)B(9)H(9)Me(2))] with PPh(3) was investigated and the product, [exo-nido-Rh(PPh(3))(2)(eta(5)-C(2)B(9)H(10)Me(2))], which is in an equilibrium with the close analogue was characterized by P-31 {H-1}, H-1, C-13 and B-11 NMR spectroscopy. A mechanism for the complex formation is suggested which is related to,the previously reported reactions between the 16-electron complex and PR(3) (R = Me and Et) ligands.

  DOI：

  10.1080/00945719608005125