[RuH(CO)(PPh3)2(Hbsh)] | 678141-31-6

• 英文名称: [RuH(CO)(PPh3)2(Hbsh)]
• CAS: 678141-31-6
• 化学式: C₅₁H₄₂N₂O₃P₂Ru
• 分子量: 893.924
• InChiKey: LEZDEZRTGSUITG-TVKYJBGJSA-M

反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 salicylaldazine 在 KOH 作用下， 以 甲醇 为溶剂， 以68%的产率得到[RuH(CO)(PPh3)2(Hbsh)]
  参考文献：
  名称：

  Mononuclear hydridocarbonyl ruthenium complexes incorporating N2O2 bis-chelating ligands

  摘要：

  The reactions of [RuH(CO)Cl(PPh3)(3)] with N,N'-bis(salicylidine)-hydrazine (H(2)bsh) and N,N'-bis(salicylidine)-p-phenylene diammine (H(2)bsp) in presence of KOH in methanol led in the formation of neutral mononuclear complexes with the formulations [RuH(CO)(PPh3)(2)(L)] (L=Hbsh or Hbsp). These present the first examples where the ligands H(2)bsh or H(2)bsp provide only two of its available donor sites for interaction with the metal centre. The complexes have been characterized by elemental analyses, FAB-MS, IR, H-1, C-13, P-31 NMR and electronic spectral studies. Molecular structure of the representative complex [RuH(CO)(PPh3)(2)(Hbsh)] have been determined by single crystal X-ray analysis. (C) 2003 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2003.12.004