| 440124-28-7

• CAS: 440124-28-7；440352-39-6
• 化学式: C₂₄H₂₇NSi
• 分子量: 357.571
• InChiKey: ILFULHDBWUBVLD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 水 作用下， 以 氯仿 为溶剂， 反应 19.0h， 以54%的产率得到5,5'-oxybis(11-butyl-5-phenyl-5,10,11,12-tetrahydro-5l5-benzo[c]benzo[3,4][1,2]azasilolo[1,2-a][1,2]azasilol-11-ium)
  参考文献：
  名称：

  Catalyst-Free Syntheses of [2]Rotaxanes Utilizing a Pentacoordinated Hydrosilane as an End-Capping Agent

  摘要：

  A pentacoordinated hydrosilane activated by an intramolecular nitrogen silicon dative bond was utilized as an end-capping agent for catalyst-free syntheses of [2]rotaxanes. The end-capping reaction of a pseudo[2]rotaxane bearing a salicylic acid terminus with the pentacoordinated hydrosilane readily proceeded at room temperature to produce the corresponding silyl-capped [2]rotaxane.

  DOI：

  10.1021/ol100786a

文献信息

• Synthesis and Properties of Pentacoordinated Phenoxysilane and Carboxysilanes with Intramolecular Nitrogen–Silicon Coordination
  作者：Yuya Domoto、Kowichiro Saruhashi、Akihiro Fukushima、Shohei Sase、Kei Goto、Takayuki Kawashima

  DOI：10.1080/10426501003773746

  日期：2010.5.27

  Reactions of a neutral pentacoordinated monohydrosilane bearing a dative N-Si bond with phenol and benzoic acid derivatives gave the corresponding pentacoordinated phenoxysilane and carboxysilanes, respectively. X-ray crystallographic analyses of these silanes revealed that the distance of the N-Si dative bond is shortened and the pentacoordination character of the silicon center becomes greater with the increase in the electron-withdrawing character of the apical substituent on silicon.