InI3(SeMe2)2 | 1211565-04-6

• 英文名称: InI3(SeMe2)2
• CAS: 1211565-04-6
• 化学式: C₄H₁₂I₃InSe₂
• 分子量: 713.593
• InChiKey: LHIVSBFJPSVEMD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二甲基硒 、 碘化铟 以 neat (no solvent) 为溶剂， 以78%的产率得到InI3(SeMe2)2
  参考文献：
  名称：

  Dimethyl selenide complexes of copper, gallium and indium halides as potential precursors for selenium-containing chalcopyrite semiconducting materials

  摘要：

  The coordination chemistry of copper, gallium and indium halides with the simplest possible selenoether i.e. Me2Se was investigated with the aim to use the resulting complexes as precursors for selenium-containing chalcopyrite semiconducting materials. An optimized general procedure for the high yield synthesis is described and the influence of a halide ion on the structure and solubility of these metal halide dimethyl selenide complexes are discussed. These complexes were characterized by the elemental analysis, FT-IR and H-1 NMR spectroscopy as well as single crystal X-ray structures, the later Study showing them to be monomeric for gallium halides, mono- or dimeric for indium halides and either an ion-pairs or 2-D extended structure in the case of copper halides. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.047