| 176635-94-2

• CAS: 176635-94-2
• 化学式: C₄H₈O*C₉H₂₇Cl₂GaSi₄
• 分子量: 460.391
• InChiKey: UNULNBKAJCAKIO-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  gallium(III) chloride 、 tris(trimethylsilyl)silyl lithium * 3 tetrahydrofuran 以 乙醚 为溶剂， 生成 、
  参考文献：
  名称：

  Reactions of gallium(III) chloride with Li[E(SiMe₃)₃](E = Si or Ge): crystal structure of (R₃Ge)ClGa(µ-OEt)₂GaCl(GeR₃)(R = SiMe₃)

  摘要：

  Reactions of Li(ER(3))(thf)(x) (E = Si or Ge, R = SiMe(3), thf = tetrahydrofuran) with gallium(III) chloride were carried out in diethyl ether with 1:1 and 2:1 stoichiometries. The 1:1 reactions gave products that decomposed upon recrystallization from pentane or drying in vacuo. The NMR spectra were consistent with a mixture of Li[R(3)SiGaCl(3)](thf)(4) (major) and GaCl4(SiR(3)). thf (minor) in the case of E = Si and GaCl2(GeR3). thf for E = Ge. The 2: 1 E = Ge reactions gave a mixture of two products exhibiting needle and plate crystal morphologies. The NMR spectra and a partial structure determination identified the former as Li[R(3)GeGaCl(3)](thf)(4). A full structure determination of the latter showed it to be the diethoxy-bridged dimer, (R(3)Ge)ClGa(mu-OEt)(2)GaCl(GeR(3)). The latter product is thought to result from cleavage of the ether solvent by either Ga2Cl6 or the intermediate gallium complex. Possible pathways are discussed.

  DOI：

  10.1039/dt9960004183