| 155022-18-7

• CAS: 155022-18-7
• 化学式: C₁₆H₂₂ClN₂Ru*Cl
• 分子量: 414.34
• InChiKey: RTZHHNUKAFIOGN-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 以 乙醇 为溶剂， 以70%的产率得到[(η6-p-cymene)Ru(o-phenylenediamine)Cl]PF6
  参考文献：
  名称：

  Reactivity of [(η6-arene)RuCl(μ-Cl)2] towards some potentially bidentate ligands. Molecular structure of [(η6-p-cymene)RuCl(taz)]PF6 (p-cymene = p-MeC6H4CH-Me2; taz = 2,6-dimethyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine)

  摘要：

  Reactions of [{(eta6-arene)RuCl(mu-Cl)}2] [arene = benzene or p-cymene (p-isopropyltoluene)] have been carried out with 4-cyanopyridine (4-CNpy), o-aminophenol (oap), o-phenylenediamine (opda), p-phenylenediamine (ppda) and 2,6-dimethyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (taz). The isolated complexes are of the types [(eta6-C6H6)RuCl2L] [L = 4-CNpy (Ia) or oap (IIa)]. [(eta6-C6H6)RuClL2]Cl [L = oap (IIIa); L2 (bidentate) = opda (IVa) or taz (VIa)] or [{(eta6-C6H6)Cl2Ru}2mu-ppda)] (VIIIa). Complexes IVa and VIa undergo anion exchange with KPF6 to give the corresponding hexafluorophosphates (Va and Vlla). The p-cymene analogues (Ib-VIIIb) have been obtained. Conductance measurements, thermogravimetry and spectroscopic (IR and H-1 and C-13 NMR) methods have been used to study the new compounds. The structure of VIIb was determined by X-ray diffraction methods. The ruthenium atom of the cation of VIIb is coordinated by the 4-amino (Ru-N = 2.14O(2) angstrom) and 3-thioxo (Ru-S = 2.354(1) angstrom) groups of the triazine and a chloride ligand (Ru-Cl = 2.394(1) angstrom). The eta6-p-cymene ring completes the hexacoordination.

  DOI：

  10.1016/0022-328x(94)88016-6
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 邻苯二胺 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Reactivity of [(η6-arene)RuCl(μ-Cl)2] towards some potentially bidentate ligands. Molecular structure of [(η6-p-cymene)RuCl(taz)]PF6 (p-cymene = p-MeC6H4CH-Me2; taz = 2,6-dimethyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine)

  摘要：

  Reactions of [{(eta6-arene)RuCl(mu-Cl)}2] [arene = benzene or p-cymene (p-isopropyltoluene)] have been carried out with 4-cyanopyridine (4-CNpy), o-aminophenol (oap), o-phenylenediamine (opda), p-phenylenediamine (ppda) and 2,6-dimethyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (taz). The isolated complexes are of the types [(eta6-C6H6)RuCl2L] [L = 4-CNpy (Ia) or oap (IIa)]. [(eta6-C6H6)RuClL2]Cl [L = oap (IIIa); L2 (bidentate) = opda (IVa) or taz (VIa)] or [{(eta6-C6H6)Cl2Ru}2mu-ppda)] (VIIIa). Complexes IVa and VIa undergo anion exchange with KPF6 to give the corresponding hexafluorophosphates (Va and Vlla). The p-cymene analogues (Ib-VIIIb) have been obtained. Conductance measurements, thermogravimetry and spectroscopic (IR and H-1 and C-13 NMR) methods have been used to study the new compounds. The structure of VIIb was determined by X-ray diffraction methods. The ruthenium atom of the cation of VIIb is coordinated by the 4-amino (Ru-N = 2.14O(2) angstrom) and 3-thioxo (Ru-S = 2.354(1) angstrom) groups of the triazine and a chloride ligand (Ru-Cl = 2.394(1) angstrom). The eta6-p-cymene ring completes the hexacoordination.

  DOI：

  10.1016/0022-328x(94)88016-6
• 作为试剂：
  描述：

  特戊醛 在 (CH₃C₆H₄CH(CH₃)2)RuCl((NH₂)2C₆H₄)⁽¹⁺⁾*Cl^(1-)={(CH₃C₆H₄CH(CH₃)2)RuCl((NH₂)2C₆H₄)}Cl 、 水 作用下， 以 1,4-二氧六环 为溶剂， 反应 20.0h， 以86%的产率得到三甲基乙酸
  参考文献：
  名称：

  （对-异丙基）钌预催化剂对醛-水变换反应的高催化效率和高选择性

  摘要：

  已证明，（对-氰基甲基）Ru II配合物家族是使用水作为氧化剂将醛氧化为羧酸的有效预催化剂。该反应被称为“醛-水变换”（AWS），先前已证明与醛歧化竞争。对于少数报道的用于该反应的单核催化剂，观察到对AWS的高选择性和低转化率或对AWS的低选择性和高转化率。均质的预催化剂，对所需的AWS和本文报道了将醛转化为产物的高效高效催化剂。另外，发现催化剂活性对于产生相应的羧酸和氢气的各种空间上不受阻碍的脂族醛是通用的。

  DOI：

  10.1021/acscatal.6b02130