[Ni(tetraethylpentamine)][ReCl6] | 840454-35-5

• 英文名称: [Ni(tetraethylpentamine)][ReCl6]
• CAS: 840454-35-5
• 化学式: C₈H₂₃N₅Ni*Cl₆Re
• 分子量: 646.919
• InChiKey: UCWUZGHJJCMUDR-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 tetrabutylammonium hexachlororhenate(IV) 、 四乙烯五胺 以 甲醇 为溶剂， 以96%的产率得到[Ni(tetraethylpentamine)][ReCl6]
  参考文献：
  名称：

  Ferrimagnetic, bimetallic chain systems: [Ni(tetren)]ReCl6 and [Ni(tetren)]ReCl6·CH3OH where tetren=tetraethylenepentamine

  摘要：

  Reaction of nikiel (H) chloride with tetraethylenepentamine (tetren) and tetrabutylammonium, hexachlororhenate [Bu4N](2)ReCl6 produced a new kind of binuclear compounds: [Ni(tetren)]ReCl6 (1) and [Ni(tetren)]ReCl6 - CH3OH (2) in which [ReCl6](2-) anions and [Ni(tetren)](2+) cations are held united by electrostatic forces. The magnetic behaviour of 1 and 2 has been investigated over the temperature range 1.7-300 K. Compound 1 behaves as a ferrimagnetic Ni-II Re-IV bimetallic, one-dimensional (1D) chain with intrachain antiferromagnetic coupling. A hysteresis loop characteristic of a soft magnet has been obtained. Compound 2 shows weak antiferromagnetic interactions within Ni-II-Re-IV units. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.07.042