| 155805-48-4

• CAS: 155805-48-4
• 化学式: C₂₀H₂₄Cl₈O₂Ti₂
• 分子量: 675.793
• InChiKey: HCYWMILAZBOFGA-UHFFFAOYSA-F

反应信息

• 作为反应物：
  描述：

  1-甲氧基-1-(三甲基甲硅氧基)-2-甲基-1-丙烯 、 以 甲苯 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Mechanism of the Mukaiyama Aldol Reaction: The First Solid-State Characterization of a Trichlorotitanium Aldolate

  摘要：

  The reaction of the silyl ketene acetal Me2C=C(OMe)OSiMes (1) with preformed TiCl4 carbonyl adducts (the monomeric [PhC(O)C(O)PhTiCl4] (2) and the dimeric {[MesCHOTi(Cl)3]2(mu-Cl)2} (Mes = 2,4,6-Me3C6H2; 3)) led to the isolation and structural characterization of the corresponding titanium aldolate complexes {[(PhCO)PhC(O)C(Me2)C(OMe)OTi(Cl)2]2(mu-Cl)2} (4) and {[MesCH(O)C(Me2)C(OMe)OTi(Cl)2]2(mu-Cl)2} (5), in which the aldolate fragment functions as a bidentate ligand in dimeric titanium complexes bridged by two chlorine atoms. Crystallographic details: 4 is monoclinic, space group P2(1)/n, with a = 9.029(1) angstrom, b = 17.468(2) angstrom, c - 13.165(2) angstrom, beta = 98.81(2)-degrees, Z = 2, and R = 0.53.

  DOI：

  10.1021/om00017a087
• 作为产物：
  描述：

  2,4,6-三甲基苯甲醛 、 四氯化钛 以 甲苯 为溶剂， 以53%的产率得到
  参考文献：
  名称：

  Cozzi, Pier Giorgio; Solari, Euro; Floriani, Carlo, Chemische Berichte, 1996, vol. 129, # 11, p. 1361 - 1368

  摘要：

  DOI：