(η(5)-C5H4(CH2)3CH3)2Mo2(CO)2(μ-η(1),η(2)-CO)(μ-η(2:2)-3-hexyne) | 211747-37-4

• 英文名称: (η(5)-C5H4(CH2)3CH3)2Mo2(CO)2(μ-η(1),η(2)-CO)(μ-η(2:2)-3-hexyne)
• CAS: 211747-37-4
• 化学式: C₂₇H₃₆Mo₂O₃
• 分子量: 600.461
• InChiKey: DULSPLISLXJJHQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (η(5)-C5H4(CH2)3CH3)2Mo2(CO)4(μ-η(2:2)-3-hexyne) 以 solid matrix 为溶剂， 生成 (η(5)-C5H4(CH2)3CH3)2Mo2(μ-CO)3(μ-η(2:2)-3-hexyne) 、 (η(5)-C5H4(CH2)3CH3)2Mo2(CO)2(μ-η(1),η(2)-CO)(μ-η(2:2)-3-hexyne)
  参考文献：
  名称：

  Photolysis of (η5-C5H4C4H9)2Mo2(CO)4(μ-η2:2-RCCR′) in frozen Nujol matrices

  摘要：

  A series of compounds, (eta (5)-C5H4C4H9)(2)Mo-2(CO)(4)(mu-eta (2:2)-acetylene), where acetylene = 3-hexyne, diphenylacetylene, phenylacetylene and 1-phenylpropyne, was prepared and characterized by IR,H-1- and C-13-NMR spectroscopies and MS. Photolysis of these compounds was carried out in frozen Nujol at 77 K. IR spectra established the presence of two isomeric carbonyl-loss species, (eta 5-C5H4C4H9)(2)Mo-2(CO)(2)(mu -eta(1),eta(2)-CO)(mu-eta(2:2)-acetylene), A, and (eta(5)-C5H4C4H9)(2)Mo-2(mu-CO)(3)(mu-eta(2:2)-acetylene), B. A is formed by photolysis into low energy electronic transitions associated with the tetrahedrane core of the parent molecule, while B is formed by either photolysis into electronic bands associated with A, or photolysis into the high energy charge-transfer bands of the parent molecule. These photointermediates are likely to be involved in the formation of 'fly-over' compounds, resulting from thermally or photochemically induced multiple substitution of acetylenes. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00512-9