[di-μ-methoxytetrachlorobis(2-methoxyphenylmethyl)-2-mercaptophenylamino(1-)-N,S]ditin(IV) | 158477-35-1

• 英文名称: [di-μ-methoxytetrachlorobis(2-methoxyphenylmethyl)-2-mercaptophenylamino(1-)-N,S]ditin(IV)
• CAS: 158477-35-1
• 化学式: C₃₀H₃₄Cl₄N₂O₄S₂Sn₂
• 分子量: 929.975
• InChiKey: VYJKIHGYTUGWRF-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  邻甲氧基苯甲醛 、 2-氨基苯硫醇 、 tin(ll) chloride 在 methanol 作用下， 以 甲醇 为溶剂， 以40%的产率得到[di-μ-methoxytetrachlorobis(2-methoxyphenylmethyl)-2-mercaptophenylamino(1-)-N,S]ditin(IV)
  参考文献：
  名称：

  A dimeric tin(IV) complex derived from the reaction of 2-(2-methoxyphenyl)benzothiazole with tin(II) chloride

  摘要：

  The condensation of 2-methoxybenzaldehyde with 2-aminothiophenol resulted in the formation of 2-(2-methoxyphenyl)benzothiazole (1), which, when reacted with anhydrous tin(II) chloride, led to the ring-opening of 1 via C-S bond rupture followed by complexation of the resulting ligand to the tin atom via the nitrogen and sulphur atoms. This gives rise to the dimeric tin(IV) complex [di-mu-methoxytetrachlorobis(2-methoxyphenyl-methyl-2-mercaptophenylamino(1-)-N,S]ditin(IV) (2), in which the methoxy oxygen atoms bridge the two tin moieties. X-ray diffraction studies were performed on 1 and 2 and the results are discussed.

  DOI：

  10.1016/s0277-5387(00)81507-7