| 1414025-44-7

• CAS: 1414025-44-7
• 化学式: C₄₂H₃₇FeNO₃P₂S₂
• 分子量: 785.687
• InChiKey: CGHRLASRQJJKIE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 sodium hydroxide 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 5.0h， 以22%的产率得到
  参考文献：
  名称：

  Light-Driven Electron Transfer between a Photosensitizer and a Proton-Reducing Catalyst Co-adsorbed to NiO

  摘要：

  While intermolecular hole-hopping along the surface of semiconductors is known, there are no previous examples of electron-hopping between molecules on a surface. Herein, we present the first evidence of electron transfer from the photoreduced sensitizer, Coumarin-343 (C343) to complex 1, both bound on the surface of NiO. In solution, 1 has been shown to be a mononuclear Fe-based proton-reducing catalyst. The reduction of 1 is reversible and occurs within 50 ns after excitation of C343. Interfacial recombination between the reduced 1((-)) and NiO hole occurs on a 100 mu s time scale by non-exponential kinetics. The observed process is the first essential step in the photosensitized generation of Hz from a molecular catalyst in the absence of a sacrificial donor reagent.

  DOI：

  10.1021/ja3082268
• 作为产物：
  描述：

  苯甲醇 在 三乙胺 作用下， 以 甲醇 、 水 为溶剂， 反应 26.5h， 生成
  参考文献：
  名称：

  Light-Driven Electron Transfer between a Photosensitizer and a Proton-Reducing Catalyst Co-adsorbed to NiO

  摘要：

  While intermolecular hole-hopping along the surface of semiconductors is known, there are no previous examples of electron-hopping between molecules on a surface. Herein, we present the first evidence of electron transfer from the photoreduced sensitizer, Coumarin-343 (C343) to complex 1, both bound on the surface of NiO. In solution, 1 has been shown to be a mononuclear Fe-based proton-reducing catalyst. The reduction of 1 is reversible and occurs within 50 ns after excitation of C343. Interfacial recombination between the reduced 1((-)) and NiO hole occurs on a 100 mu s time scale by non-exponential kinetics. The observed process is the first essential step in the photosensitized generation of Hz from a molecular catalyst in the absence of a sacrificial donor reagent.

  DOI：

  10.1021/ja3082268