[Ir(CO)2(acac)(OTf)]2 | 1124346-22-0

• 英文名称: [Ir(CO)2(acac)(OTf)]2
• 英文别名: [Ir(CO)2(2,4-pentanedionato)(OTf)]2
• CAS: 1124346-22-0
• 化学式: C₁₆H₁₄F₆Ir₂O₁₄S₂
• 分子量: 992.841
• InChiKey: JIPHEUMXTBDPHG-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Ir(CO)2(acac)(OTf)]2 在 KC₈ 作用下， 以 二氯甲烷 为溶剂， 以83%的产率得到(acetylacetonato)dicarbonyliridium(I)
  参考文献：
  名称：

  Serendipitous Discovery of a Simple Compound with an Unsupported Ir−Ir Bond

  摘要：

  The long-known compound Ir(acac)(CO)(2) (acac = 2,4-pentanedionato) undergoes a formal oxidation reaction when treated with AgOTf (Tf = CF3SO2) to give the dinuclear complex [Ir(acac)(OTf)(CO)(2)](2), containing an unsupported Ir-Ir bond. The compound has been characterized by a single-crystal X-ray diffraction study, and DFT and NBO calculations have been employed to probe the nature of the Ir-Ir bond. Reduction of the complex regenerates Ir(acac)(CO)(2).

  DOI：

  10.1021/om801110x
• 作为产物：
  描述：

  (acetylacetonato)dicarbonyliridium(I) 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以60%的产率得到[Ir(CO)2(acac)(OTf)]2
  参考文献：
  名称：

  Serendipitous Discovery of a Simple Compound with an Unsupported Ir−Ir Bond

  摘要：

  The long-known compound Ir(acac)(CO)(2) (acac = 2,4-pentanedionato) undergoes a formal oxidation reaction when treated with AgOTf (Tf = CF3SO2) to give the dinuclear complex [Ir(acac)(OTf)(CO)(2)](2), containing an unsupported Ir-Ir bond. The compound has been characterized by a single-crystal X-ray diffraction study, and DFT and NBO calculations have been employed to probe the nature of the Ir-Ir bond. Reduction of the complex regenerates Ir(acac)(CO)(2).

  DOI：

  10.1021/om801110x