dichloro[3,4,7,8,11,12,15,16-tetrabenzo-2,5,10,13-tetraazacyclohexadecane-1,5,9,13-tetraene]cobalt(II) | 217787-63-8

• 英文名称: dichloro[3,4,7,8,11,12,15,16-tetrabenzo-2,5,10,13-tetraazacyclohexadecane-1,5,9,13-tetraene]cobalt(II)
• 英文别名: [Co(tetrabenzo[b,f,j,n][1,4,9,12]tetraazacyclohexadecine)Cl2]
• CAS: 217787-63-8
• 化学式: C₂₈H₂₀Cl₂CoN₄
• 分子量: 542.393
• InChiKey: XTCDFKZNLQTUEX-JTPCSISISA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  邻苯二胺 以 甲醇 、 乙醇 为溶剂， 生成 dichloro[3,4,7,8,11,12,15,16-tetrabenzo-2,5,10,13-tetraazacyclohexadecane-1,5,9,13-tetraene]cobalt(II)
  参考文献：
  名称：

  Metal ion-directed synthesis of 16-membered tetraazamacrocyclic complexes and their physico-chemical studies

  摘要：

  Complexes of Co(II), Ni(II), Cu(II) and Zn(II) containing macrocyclic tetradentate nitrogen donor (N-4) ligand have been synthesized from the template condensation reaction between o-phthalaldehyde and o-phenylenediamine. The newly synthesized ligand and its complexes have been characterized on the basis of results of elemental analysis, molar conductance, magnetic susceptibility measurements, FT-IR, electronic, H-1 FT NMR spectral data and Job's method. Their thermal behaviour has been studied by the thermogravimetric analysis. An octahedral geometry has been proposed for all of these complexes except the copper complexes, which show distorted octahedral geometry. The low conductivity data suggest their non-ionic nature. The biological activities of the metal complexes have also been studied against different bacteria. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.07.050

文献信息

• Synthesis, spectral studies and antibacterial activity of novel macrocyclic Co(II) compounds
  作者：P. Muralidhar Reddy、Adapa V.S.S. Prasad、Kanne Shanker、Vadde Ravinder

  DOI：10.1016/j.saa.2007.03.002

  日期：2007.11

  Ten novel macrocyclic Co(II) compounds have been synthesized by treating four N(4) and six N(2)O(2) donor macrocycles with cobalt chloride in methanol. These compounds were characterized by elemental, IR, (1)H, (13)C NMR, mass, electronic spectral analysis, molar conductance and magnetic susceptibility measurements. Thermal behavior of these compounds has been studied by the thermogravimetric analysis

  十个新型大环Co（II）化合物已通过在甲醇中用氯化钴处理四个N（4）和六个N（2）O（2）供体大环来合成。这些化合物的特征在于元素，IR，（1）H，（13）C NMR，质量，电子光谱分析，摩尔电导和磁化率测量。通过热重分析研究了这些化合物的热行为。已经为所有这些络合物提出了八面体几何形状。筛选所有大环化合物和大环Co（II）化合物以及现有的抗菌药物对革兰氏+ ve和革兰氏-ve细菌的抗菌活性。与链霉素和氨苄青霉素相比，所有这些化合物都具有更高的活性。