Ru3(CO)10(μ3-η(2):η(2):η(2)-C6H5-(η(2)-CCH3CH2)) | 164663-48-3

• 英文名称: Ru3(CO)10(μ3-η(2):η(2):η(2)-C6H5-(η(2)-CCH3CH2))
• CAS: 164663-48-3
• 化学式: C₁₉H₁₀O₁₀Ru₄
• 分子量: 802.562
• InChiKey: WBBDCFVYPSOIGS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-苯基-1-丙烯 、 十二羰基三钌 以 正辛烷 为溶剂， 以12%的产率得到Ru3(CO)10(μ3-η(2):η(2):η(2)-C6H5-(η(2)-CCH3CH2))
  参考文献：
  名称：

  Synthesis and molecular structure of tetraruthenium clusters carrying facial arene ligands

  摘要：

  Ru3(CO)12与1,3-二异丙苯（C6H4-{CMeCH2}2-1,3）和异丙苯（C6H5-{CMeCH2}）在回流辛烷中发生反应，生成新物种Ru4(CO)9(μ3-η2:η2：η2-C6H4{η2-CMeCH2}2-1,3）和 Ru4(CO)10（µ3-η2:η2:η2-C6H5{η2-CMeCH2}）。

  DOI：

  10.1039/c39950000537

文献信息

• Synthesis and Characterization of Ru3 and Ru4 Clusters with Isopropenylbenzene and Diisopropenylbenzene Ligands
  作者：Dario Braga、Janice J. Byrne、Fabrizia Grepioni、Emilio Parisini、Paul J. Dyson、Petra E. Gaede、Brian F. G. Johnson、David Reed

  DOI：10.1021/om00010a060

  日期：1995.10

  The four clusters Ru-3(CO)(7)(mu(3)-eta(2):eta(2):eta(2)-C6H4-eta(2)-CCH3CH2}(2)-1,3), 1, Ru-4(CO)(9)(mu(3)-eta(2):eta(2):eta(2)- C6H4-eta(2)-CCH3CH2}(2)-1,3), 2, Ru-3(CO)(8)(mu(3)-eta(2):eta(2):eta(2)-C6H5-eta(2)-CCH3CH2}), 3, and Ru-4(CO)(10)- (mu(3)-eta(2):eta(2):eta(2)-C6H5-eta(2)-CCH3CH2}), 4, have been prepared and characterized both spectroscopically and by means of single-crystal X-ray diffraction. The presence of the propenyl substituent(s) on the aromatic ligands results in the observed preference of the rings toward a facial coordination mode, formally donating all their pi-electrons to the metal cluster unit.