(3-aminopyridine(+H))(3-aminopyridine(+2H))[hexachlorobismuthate] | 1312891-98-7

• 英文名称: (3-aminopyridine(+H))(3-aminopyridine(+2H))[hexachlorobismuthate]
• 英文别名: (3-AmpH)(3-AmpH2)[BiCl6]
• CAS: 1312891-98-7
• 化学式: BiCl₆*C₅H₇N₂*C₅H₈N₂
• 分子量: 612.954
• InChiKey: DNVJBWIEELNCIU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-氨基吡啶 、 氯化铋 在 aq. HCl 作用下， 以 盐酸 为溶剂， 以75%的产率得到(3-aminopyridine(+H))(3-aminopyridine(+2H))[hexachlorobismuthate]
  参考文献：
  名称：

  Stabilization of [BiCl6]3− and [Bi2Cl10]4− with various organic precursors as cations leading to inorganic–organic supramolecular adducts: Syntheses, crystal structures and properties of [C5H7N2]3[BiCl6], [C5H7N2][C5H8N2][BiCl6] and [C10H10N2]2[Bi2Cl10]

  摘要：

  Syntheses, crystal structures and properties of three ion pair compounds [C5H7N2](3)[BiCl6] (1), [C5H7N2][C5H8N2][BiCl6] (2) and [C10H10N2](2)[Bi2Cl10] (3) have been described. Compounds 1 and 2 crystallize in triclinic system (space group, P-1), whereas compound 3 crystallizes in monoclinic sysyem (space group, P2(1)/c). In their crystal structures, supramolecular hydrogen bonding interactions between bismuth-chloro anion and organic cation play an important role in the stabilization of [BiCl6](3) and [Bi2Cl10](4) anions in the title ion pair compounds. Compounds 1, 2 and 3 are characterized by routine spectral analyses and elemental analyses, besides crystal structure determinations. Compounds 1, 2 and 3 are additionally characterized by thermogravimetric analyses. Compound [C5H7N2][C5H8N2][BiCl6] (2) exhibits emission spectrum at room temperature in the visible region. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.109