[(N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine)Mn(Cl)(methanol)]ClO4 | 882530-14-5

• 英文名称: [(N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine)Mn(Cl)(methanol)]ClO4
• 英文别名: [(bpppa)Mn(Cl)(methanol)]ClO4
• CAS: 882530-14-5
• 化学式: C₂₅H₃₂ClMnN₄O₂*ClO₄
• 分子量: 610.396
• InChiKey: BWWBEXHGZQHVNJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine)Mn(Cl)(methanol)]ClO4 以 neat (no solvent, solid phase) 为溶剂， 生成 [(N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine)Mn(Cl)]ClO4
  参考文献：
  名称：

  Synthesis and characterization of a series of N3O-ligated mononuclear Mn(II) halide complexes

  摘要：

  Treatment of a N3O-donor chelate ligand (mpppa=N-methyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylethyl)amine; bpppa = N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine) with equimolar amounts of Mn(ClO4)(2) center dot 6H(2)O and Me4NX (X = Cl, Br, 1) in methanol resulted in the production of a series of mononuclear Mn(H) halide complexes of the formula [(L)Mn-X(CH3OH)]ClO4 (L = mpppa or bpppa). X-ray crystallographic studies of [(mpppa)Mn-Cl(CH3OH)]ClO4 center dot CH3OH (2 center dot CH3OH), [(mpppa)Mn-Br(CH3OH)]ClO4 center dot CH3OH (4 center dot CH3OH), [(mpppa)Mn-I(CH3OH)]ClO4 center dot CH3OH (6 center dot CH3OH), and [(bpppa)Mn-I(CH3OH)]ClO4 center dot O-2(CH2CH3)(2) (7 center dot O(CH2CH3)(2)) revealed for each a mononuclear Mn(II) center having tetradentate coordination of the chelate ligand, one coordinated halide anion, and one molecule of coordinated methanol. An increase in the Mn-X distance through the halide series (Cl, Br, 1) correlates linearly with the increase in the radius of the anion. The magnetic moment of each halide complex, measured via Evans method in methanol, is consistent with the presence of a high-spin distorted octahedral Mn(11) center. The EPR features of the halide complexes in methanol do not change as a function of the nature of the halide coordinated to the Mn(II) center. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.008
• 作为产物：
  描述：

  N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine 、 甲醇 、 manganese(II) perchlorate hexahydrate 、 四甲基氯化铵 以 甲醇 为溶剂， 以84%的产率得到[(N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine)Mn(Cl)(methanol)]ClO4
  参考文献：
  名称：

  Synthesis and characterization of a series of N3O-ligated mononuclear Mn(II) halide complexes

  摘要：

  Treatment of a N3O-donor chelate ligand (mpppa=N-methyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylethyl)amine; bpppa = N-benzyl-N-((6-pivaloylamido-2-pyridyl)methyl)-N-(2-pyridylmethyl)amine) with equimolar amounts of Mn(ClO4)(2) center dot 6H(2)O and Me4NX (X = Cl, Br, 1) in methanol resulted in the production of a series of mononuclear Mn(H) halide complexes of the formula [(L)Mn-X(CH3OH)]ClO4 (L = mpppa or bpppa). X-ray crystallographic studies of [(mpppa)Mn-Cl(CH3OH)]ClO4 center dot CH3OH (2 center dot CH3OH), [(mpppa)Mn-Br(CH3OH)]ClO4 center dot CH3OH (4 center dot CH3OH), [(mpppa)Mn-I(CH3OH)]ClO4 center dot CH3OH (6 center dot CH3OH), and [(bpppa)Mn-I(CH3OH)]ClO4 center dot O-2(CH2CH3)(2) (7 center dot O(CH2CH3)(2)) revealed for each a mononuclear Mn(II) center having tetradentate coordination of the chelate ligand, one coordinated halide anion, and one molecule of coordinated methanol. An increase in the Mn-X distance through the halide series (Cl, Br, 1) correlates linearly with the increase in the radius of the anion. The magnetic moment of each halide complex, measured via Evans method in methanol, is consistent with the presence of a high-spin distorted octahedral Mn(11) center. The EPR features of the halide complexes in methanol do not change as a function of the nature of the halide coordinated to the Mn(II) center. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.008