(Me2Si)[(η(5)-t-heptyl-C5H3)Fe(CO)]2(μ-CO)2 | 207996-28-9

• 英文名称: (Me2Si)[(η(5)-t-heptyl-C5H3)Fe(CO)]2(μ-CO)2
• 英文别名: cis-(Me2Si)[(η(5)-t-heptyl-C5H3)Fe(CO)]2(μ-CO)2
• CAS: 207996-28-9；207924-19-4
• 化学式: C₃₀H₄₂Fe₂O₄Si
• 分子量: 606.441
• InChiKey: JIQBFTIHBAONOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五羰基铁 、 以 xylene 为溶剂， 以45%的产率得到(Me2Si)[(η(5)-t-heptyl-C5H3)Fe(CO)]2(μ-CO)2
  参考文献：
  名称：

  Synthesis and characterization of a series of sila-bridged diiron complexes (E)[(η5-t-BuC5H3)Fe(CO)]2(μ-CO)2 (E=Me2Si, Me2SiSiMe2, Me2SiOSiMe2). The molecular structures of cis- and trans-(Me2Si)[η5-t-BuC5H3)Fe(CO)]2(μ-CO)2

  摘要：

  Binuclear iron complexes (E)[(eta(5)-t-BuC5H3)Fe(CO)](2)(mu-CO)(2) [E = Me2Si (1), Me2SiOSiMe2(3)] were prepared by reaction of Fe(CO)(5) with the corresponding cyclopentadienyl ligands in boiling xylene. Like the analogue (Me2SiSiMe2)[(eta(5)-t-BuC5H3)Fe(CO)](2)(mu-CO)(2) (2) reported previously, they are also found to exist as a mixture of cis and trans isomers that have been separated by preparative TLC. To examine the effect of larger substituents on the formation of isomers, the analogue (Me2Si)[{eta(5)C(5)H(3)(t-heptyl)}Fe(CO)](2)(mu-CO)(2) (4) was also synthesized by the same approach. The molecular structures of cis- and trans-(Me2Si)[(eta(5)-t-BuC5H3)Fe(CO)](2)(mu-CO)(2) have been determined by X-ray diffraction. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00462-2