[Ag(5,5'-bipyrimidine)(PF6)](n) | 960128-61-4

• 英文名称: [Ag(5,5'-bipyrimidine)(PF6)](n)
• CAS: 960128-61-4
• 化学式: Ag*C₈H₆N₄*F₆P
• 分子量: 410.995
• InChiKey: YZGPOVBQEOYUSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Ag(5,5'-bipyrimidine)(OTf)](n) 、 hexafluorophosphate anion 以 水 为溶剂， 生成 [Ag(5,5'-bipyrimidine)(PF6)](n)
  参考文献：
  名称：

  Toward Quartz and Cristobalite:  Spontaneous Resolution, Structures, and Characterization of Chiral Silica−Mimetic Silver(I)−Organic Materials

  摘要：

  An alpha-quartz-mimetic chiral coordination network of [Ag(L-1)(CF3-SO3)](n) (L-1 = 5,5'-bipyrimidine), after treatment with PF6- anions, undergoes a solution-state structural transformation toward [Ag-(L-1)(PF6)](n) with a cristobalite-mimetic chiral structures. This structural transformation is accompanied by substantial enhancement in the fluorescent intensity and in the second-harmonic-generation response. The results also demonstrate an effective design strategy based on the spontaneous resolution route for the preparation of chiral architectures.

  DOI：

  10.1021/ic701412q