μ-chloro-bis[(1R*,4R*)-5,5,7,13,15,15-hexamethyl-1,4,8,12-tetraazacyclopentadeca-7,12-dieneN(1),N(4),N(8),N(12)(perchlorato-O)copper(II)] perchlorate | 179633-05-7

• 英文名称: μ-chloro-bis[(1R*,4R*)-5,5,7,13,15,15-hexamethyl-1,4,8,12-tetraazacyclopentadeca-7,12-dieneN(1),N(4),N(8),N(12)(perchlorato-O)copper(II)] perchlorate
• 英文别名: (9R*,12R*)-(6,8,8,13,13,15-hexamethyl-1,5,9,12-tetrazacyclopentadeca-5,15(1)-diene-N(1),N(5),N(9),N(12))copper(II) Cl(ClO4)3
• CAS: 179633-05-7
• 化学式: C₃₄H₆₈Cl₃Cu₂N₈O₈*ClO₄
• 分子量: 1049.86
• InChiKey: JYIQOXUNOLEFER-WBFXXQSJSA-J

反应信息

• 作为产物：
  描述：

  lithium chloride 、 [(copper)(6,8,8,13,13,15-hexamethyl-1,5,9,12-tetraazacyclopentadeca-5,15(1)-diene)] (perchlorate)2 以 水 为溶剂， 生成 μ-chloro-bis[(1R*,4R*)-5,5,7,13,15,15-hexamethyl-1,4,8,12-tetraazacyclopentadeca-7,12-dieneN(1),N(4),N(8),N(12)(perchlorato-O)copper(II)] perchlorate
  参考文献：
  名称：

  A Chloro-Bridged Dinuclear Copper(II) Cationic Complex of a 15-Membered Tetraaza Macrocyclic Ligand

  摘要：

  The title complex, mu-chloro-bis[(1R*,4R*)-5,5,7,13,15, 15-hexamethyl-1,4,8,12-tetraazacyclopentadeca-7,12-diene-N-1, N-4,N-8,N-12)(perchlorato-O)copper(II)] perchlorate, [Cu2Cl(ClO4)(2)(C17H34N4)(2)](ClO4), has a chloride-bridged centrosymmetric confacial dinuclear cation. Each copper(II) ion has tetrahedrally twisted (+/- 0.30 Angstrom) planar coordination composed of the four N atoms of the macrocyclic ligand [mean Cu-N-amine 2.02 (1) and Cu-Ni-imine 1.99 (1) Angstrom], with weak tetragonal chloride [Cu-Cl 2.83 (1) Angstrom] and perchlorate O-atom [Cu-O 2.94 (1) Angstrom] interactions. The Cu atom is displaced by 0.09 Angstrom from the best N-4 plane towards the chloride ion.

  DOI：

  10.1107/s0108270196002004