| 86322-15-8

• CAS: 86322-15-8
• 化学式: C₁₀H₈ClN₃NiO
• 分子量: 280.336
• InChiKey: QHEHYTYXSNSVAZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氯甲烷-D2 、 [Ni(NO)(bipy)2][PF6] 以 二氯甲烷-D2 为溶剂， 生成 [Ni(2,2'-bipyridine)₃][PF₆]₂ 、
  参考文献：
  名称：

  Formation of N₂O from a Nickel Nitrosyl: Isolation of the cis-[N₂O₂]^2– Intermediate

  摘要：

  Addition of 2,2'-bipyridine (bipy) to [Ni(NO)(bipy)][PF6] (1) results in formation of a rare five-coordinate nickel nitrosyl [Ni(NO)(bipy)(2)][PF6] (2). This complex exhibits a bent NO- ligand in the solid state. On standing in acetonitrile, 2 furnishes the NO coupled product, [Ni(kappa(2)-O2N2)(bipy)] (8) in moderate yield. Subsequent addition of 2 equiv of acetylacetone (H(acac)) to 8 results in formation of [Ni(acac)(2)(bipy)], N2O, and H2O. Preliminary mechanistic studies suggest that the N-N bond is formed via a bimetallic coupling reaction of two NO- ligands.

  DOI：

  10.1021/ja304204q