fac-Re(5-(dimethylamino)-1,10-phenanthroline)(CO)3Cl | 169232-75-1

• 英文名称: fac-Re(5-(dimethylamino)-1,10-phenanthroline)(CO)3Cl
• CAS: 169232-75-1
• 化学式: C₁₇H₁₃ClN₃O₃Re
• 分子量: 528.969
• InChiKey: DNGHVXQUILNKLZ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  五羰基氯铼(I) 、 N,N-dimethyl-1,10-phenanthrolin-5-amine 以 甲苯 为溶剂， 生成 fac-Re(5-(dimethylamino)-1,10-phenanthroline)(CO)3Cl
  参考文献：
  名称：

  A Versatile Preparative Route to 5-Substituted-1,10-Phenanthroline Ligands via 1,10-Phenanthroline 5,6-Epoxide

  摘要：

  The reactive ligand 1,10-phenanthroline-5,6-epoxide is a versatile starting material for the preparation of a variety of 5-substituted-1, 10-phenanthroline ligands by reaction with oxygen-, carbon-, or nitrogen-based nucleophiles. All of the new ligands readily form complexes with the fac-Re-1(CO)(3)Cl fragment. Of particular interest are the syntheses of the amino and aminocrown derivatives of Re-1 which can function as cation sensors by perturbation of molecular luminescence. An interesting example involving Pb2+ is presented.

  DOI：

  10.1021/ic00129a003