| 181880-00-2

• CAS: 181880-00-2
• 化学式: C₁₈H₁₆FeN₂O₇Se
• 分子量: 507.141
• InChiKey: ZRMQNGYWRIGNDP-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  、 3,5-二硝基苯甲酸 以 二氯甲烷 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Organoiron Selenium Complexes. Synthesis and Characterization oftert-Butyl Substituted Cyclopentadienyldicarbonylselenocarboxylate Iron Complexes, C_p′Fe(CO)₂SeCOR (Cp′ = C₅H₅,t-BuC₅H₄, 1,3-t-Bu₂C₅H₃)

  摘要：

  The organoiron selenides [(C5H5)Fe(CO)(2)]2(mu-Se) (I), [(t-BuC(5)H(4))Fe(CO)(2)](2)(mu-Se-2) (II), and [(1,3-t-Bu(2)C(5)H(3))Fe(CO)(2)](2)(mu-Se-2) (III) were prepared from the reaction of the organoiron dimers [(C5H5)Fe(CO)(2)](2), [(t-BuC(5)H(4))Fe(CO)(2)](2) and [(1,3-t-Bu(2)C(5)H(3))Fe(CO)(2)](2) with elemental selenium. The above selenides (I), (II) and (III) react with acid chlorides, RCOCl to give the Se-bonded monoselenocarboxylate derivatives [Cp'Fe(CO)(2)SeCOR] (Cp' = C5H5, t-BuC(5)H(4), 1,3-t-Bu(2)C(5)H(3); R = 4-O2NC6H4, 3,5-(O2N)(2)C6H3) The presence of tert-butyl substituents on the cyclopentadienyl ring introduces significant changes in the properties of these systems relative to the unsubstituted cyclopentadienyl analogues.

  DOI：

  10.1080/00945719608005133