(η8-cyclooctatetraenyl)uranium (1,3-dithiole-2-one-4,5-dithiolate) bis(pyridine) | 856890-48-7

• 英文名称: (η8-cyclooctatetraenyl)uranium (1,3-dithiole-2-one-4,5-dithiolate) bis(pyridine)
• CAS: 856890-48-7
• 化学式: C₂₁H₁₈N₂OS₄U
• 分子量: 680.68
• InChiKey: YTQYOGFUBWFTJY-CJNMVQMASA-L

反应信息

• 作为产物：
  描述：

  吡啶 、 bis[(η8-cyclooctatetraenyl)uranium (1,3-dithiole-2-one-4,5-dithiolate)] 以 吡啶 为溶剂， 以99%的产率得到(η8-cyclooctatetraenyl)uranium (1,3-dithiole-2-one-4,5-dithiolate) bis(pyridine)
  参考文献：
  名称：

  单环辛四烯基（二硫烯）铀化合物

  摘要：

  中性单核二硫烯化合物[U(cot)(dithiolene)(tppo)2][cot = η-C8H8; dithiolene = dddt (9), dmio (10), mdt (11)], [U(cot)(dithiolene)(hmpa)2] [dithiolene = dddt (12), dmio (13), mdt (14)], [U(cot)(mdt)(bipy)] (15) 和 [U(cot)(mdt)(terpy)] (16) 通过处理二聚复合物 [{U(cot)(dithiolene)}2] [dithiolene = dddt (3), dmio (4), mdt (5)] (dddt = 5,6-dihydro-1,4-dithiine-2,3-dithiolate; dmio = 1,3-dithiole-2-one -4,5-二硫醇；mdt = 1,3-二硫醇-4

  DOI：

  10.1002/ejic.200400403