| 185056-90-0

• CAS: 185056-90-0
• 化学式: C₄₈H₆₄Co₄O₈Si₅
• 分子量: 1145.43
• InChiKey: YOPQYHSKINGRTF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 tetrakis[3-[cyclopenta-2,4-dien-1-yl(dimethyl)silyl]propyl]silane 在 1,3-环己二烯 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Organometallic silicon-based dendrimers with peripheral Si-cyclopentadienyl, SiCo and SiFe σ-bonds

  摘要：

  The new cyclopentadienyl functionalized dendrimer Si[(CH2)(3)SiMe(2)(C5H5)](4) (1) has been prepared and used to pi-coordinate Co(CO)(2) moieties, affording the tetranuclear Si[(CH2)(3)SiMe(2)(eta(5)-C5H4)Co(CO)(2)](4) (2) The Si-H and Si-Cl functionalized dendrimers Si[(CH2)(3)SiMe(2)H](4) (G1H(1)) and Si[(CH2)(3)SiMe(2)Cl](4) (G1Cl(1)) have been reacted with Co-2(CO)(8) and Na+[(eta(5)-C5H5)Fe(CO)(2)](-), respectively, to yield the corresponding organometallic dendritic molecules Si[(CH2)(3)SiMe(2)Co(CO)(4)](4) (3) and Si[(CH2)(3)SiMe(2)(eta(5)-C5H5)Fe(CO)(2)](4) (4), containing peripheral Si-Co and Si-Fe sigma-bonds.

  DOI：

  10.1016/s0020-1693(96)05347-9