| 12024-77-0

• CAS: 12024-77-0
• 化学式: GdO
• 分子量: 173.249
• InChiKey: HOTISDRNVAAVPV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  gadolinium(III) oxide 生成
  参考文献：
  名称：

  The ground state and zero‐field splitting of the GdO molecule

  摘要：

  The X-band ESR spectrum of GdO was obtained in an argon matrix at 4 °K as a series of 16 fine-structure lines between 0 and 12 000 G. Analysis proved that most of these lines were due to off-principal-axis transitions and established the ground state as 9Σ. An accurate fit to the data required the inclusion of a small b40 term (quartic in Sz) besides the usual b20 = D term in the spin Hamiltonian. The derived parameters in an argon matrix are g∥ = 1.990(9), g⊥ = 1.986(5), ‖ b20 ‖ = ‖ D ‖ = 0.2078(3) cm−1, and ‖ b40 ‖ = 0.000 40(5) cm−1. The two strongest lines were also observed in a neon matrix.

  DOI：

  10.1063/1.441970