| 497224-43-8

• CAS: 497224-43-8
• 化学式: HLiS
• 分子量: 41.007
• InChiKey: HXQGSILMFTUKHI-DYCDLGHISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.0
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  lithium 、 硫化氘 以 neat (no solvent, gas phase) 为溶剂， 生成
  参考文献：
  名称：

  The millimeter/submillimeter spectrum of LiSH (X̃1A′): further investigations of the metal–sulfur bond

  摘要：

  The pure rotational spectrum of USH and its Li-6 and deuterium isotopomers has been recorded in the region 73-521 GHz using millimeter/sub-millimeter direct absorption techniques. These species were created by the reaction of H2S or D2S and lithium vapor in a dc discharge. Extensive K-a ladder structure was observed for all three isotopomers, indicating that USH is a near-prolate asymmetric top with a (X) over tilde (1)A(1) electronic state. Rotational parameters have been determined for the three species, enabling the calculation of a r(m)((1)) structure. The Li-S-H bond angle was found to be 93degrees, indicating a high degree of covalent bonding in this molecule. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(02)01504-x