4,5'-dicarbonyl-4,4,5,5'-tetrakis(trimethylphosphine)-σ[Ir(5')B(6)]-nido-5'-iridaoctaborano[3',8':1,2]-closo-4-iridadodecaborane | 181046-48-0

• 英文名称: 4,5'-dicarbonyl-4,4,5,5'-tetrakis(trimethylphosphine)-σ[Ir(5')B(6)]-nido-5'-iridaoctaborano[3',8':1,2]-closo-4-iridadodecaborane
• CAS: 181046-48-0
• 化学式: C₁₄H₅₀B₁₆Ir₂O₂P₄
• 分子量: 931.861
• InChiKey: KRVBJIJILSACDF-XYTYOJENSA-N

反应信息

• 作为产物：
  描述：

  arachno-[(CO)H(PMe3)2IrB8H12] 以 neat (no solvent) 为溶剂， 以0.5%的产率得到4,5'-dicarbonyl-4,4,5,5'-tetrakis(trimethylphosphine)-σ[Ir(5')B(6)]-nido-5'-iridaoctaborano[3',8':1,2]-closo-4-iridadodecaborane
  参考文献：
  名称：

  Macropolyhedral boron-containing cluster chemistry. Isolation and characterisation of the eighteen-vertex nido-5′-iridaoctaborano[3′,8′ : 1′,2]-closo-4-iridadodecaborane, [(CO)(PMe₃)₂IrB₁₆H₁₄Ir(CO)(PMe₃)₂]

  摘要：

  The novel eighteen-vertex macropolyhedral diiridaborane [(CO)(PMe(3))(2)IrB16H14Ir(CO)(PMe(3))(2)] has been isolated in low yield from the products of thermolysis of the nine-vertex. arachno-monoiridaborane [(CO)(PMe(3))(2)HIrB8H12], and examined by single-crystal X-ray diffraction analysis, NMR spectroscopy and mass spectrometry. The macropolyhedral framework consists pf a close-type twelve-vertex {IrB11} subcluster and a nido-type eight-vertex {IrB7} subcluster fused with two boron atoms in common; In addition there is an iridium-boron two-electron two-centre intercluster cross-linkage that is suprafacial to the open nido subcluster. The results are briefly discussed in terms of bonding schemes among individual subclusters.

  DOI：

  10.1039/dt9960003145