cis-bis(phenyl[bis(p-triisopropyloxysilylphenyl)]phosphine)dichloroplatinum | 431887-87-5

• 英文名称: cis-bis(phenyl[bis(p-triisopropyloxysilylphenyl)]phosphine)dichloroplatinum
• CAS: 431887-87-5
• 化学式: C₇₂H₁₁₀Cl₂O₁₂P₂PtSi₄
• 分子量: 1607.93
• InChiKey: HGORLRNCKDANTA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 phenyl(bis(p-triisopropyloxysilylphenyl))phosphine 以 水 、 异丙醇 为溶剂， 以66%的产率得到cis-bis(phenyl[bis(p-triisopropyloxysilylphenyl)]phosphine)dichloroplatinum
  参考文献：
  名称：

  Organic–inorganic hybrid materials containing metal phosphine complexes

  摘要：

  The hydrolysis-polycondensation of palladium (Pd) and platinum (Pt) complexes of phosphines [p-(OiPr)(3)SiC6H4](2)PC6H5 and [p-(OiPr)(3)SiC6H4](3)P gives rise to xerogels in which the metal complexes are included within a silica matrix with retention of the arrangement around the metal centre. However, the trans-Pd as well as the trans-Pt complexes incorporated within the xerogels slowly isomerize into the more stable cis complexes. Direct reaction of (CH3CN)(2)PdCl2 with xerogels; prepared from both phosphines leads to the incorporation of the Pd salt, the corresponding complexes always adopting a cis arrangement of the ligands. Treatment with nBu(3)P of all the materials containing metal centres leads to the complete removal of the metal except for the materials obtained by hydrolysis of the metal-[p-(OiPr)(3)SiC6H4](3)P Complexes. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0022-328x(01)01489-9