| 142085-02-7

• CAS: 142085-02-7
• 化学式: C₂₆H₄₉PRu
• 分子量: 493.719
• InChiKey: SXODJJFNVBRXQU-KLEHABCMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ru(η(4-)cisoid-2,3-dimethyl-1,3-butadiene)(η(4-)1,5-COD)(NCMe) 、 三丁基膦 生成
  参考文献：
  名称：

  Synthesis and protonation of new 1,3-diene complexes of zerovalent ruthenium

  摘要：

  Complexes of general formula Ru(eta-4-1,3-diene)(eta-4-1,5-cyclooctadiene)(nitrile) are formed by reaction of various acyclic 1,3-dienes with Ru(eta-6-naphthalene)(eta-4-1,5-cyclooctadiene) (1) in the presence of nitriles. The coordinated nitrile is readily replaced by stronger pi-acceptors such as CO, (t)BuNC, P(OMe)3 and tertiary phosphines. In contrast, 1,3-cyclohexadiene reacts with 1 in the presence of benzonitrile to give Ru(1,3-C6H8)2(NCPh). The mono-protonated salt obtained from the 2,3-dimethylbutadiene complex Ru(eta-4-C6H10)(eta-4-1,5-C8H12)(PEt3) and HPF6 contains an agostic methyl group whose rotation is almost frozen at -90-degrees-C.

  DOI：

  10.1016/0022-328x(92)83244-c