| 336616-59-2

• CAS: 336616-59-2
• 化学式: N₂O*O
• 分子量: 60.0122
• InChiKey: CHYSVKBLQYPCFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.22
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  79.71
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  一氧化二氮 以 gaseous matrix 为溶剂， 生成 水 、 nitric oxide anion 、
  参考文献：
  名称：

  Pulsed photoelectron spectroscopy of negative cluster ions: Isolation of three distinguishable forms of N₂O⁻₂

  摘要：

  Three different ionic species with stoichiometry N2O−2 are generated by varying the neutral precursors in an electron beam ionized free jet expansion. In each case, the ion is isolated by mass spectrometry and then probed using pulsed photoelectron spectroscopy (PES) at 532 and 355 nm (2.330 and 3.495 eV, respectively). The neutral starting materials used in the three preparations are (I) O2 seeded 5% in N2, (II) pure N2O, and (III) NO seeded 10% in Ar. Based on their PES and photofragmentation properties, the three species appear to be best described as (I) O−2 ⋅N2, (II) either O−⋅N2O or more likely a chemically bound species, and (III) NO−⋅NO. It is likely that two of these species are trapped intermediates in the O−+N2O→NO−+NO reaction, suggesting a double minimum potential energy surface. The formation mechanisms of these ions in our source are discussed in the context of previous preparation schemes.

  DOI：

  10.1063/1.454576