[Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(μ-CO)] | 1021839-15-5

• 英文名称: [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(μ-CO)]
• CAS: 1021839-15-5
• 化学式: C₂₄H₃₅Mo₂OP
• 分子量: 562.395
• InChiKey: RDBKWSPHSAJNAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [((η5-cyclopentadienyl)molybdenum(carbonyl))2(μ-methyl)(μ-dicyclohexylphosphido)] 以 甲苯 为溶剂， 生成 [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(μ-CO)]
  参考文献：
  名称：

  Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo₂(η⁵-C₅H₅)₂(μ-η¹:η²-CH₃)(μ-PCy₂)(CO)₂]: Migratory Behavior and Methylidyne Derivatives

  摘要：

  The bridging methyl ligand present in the title compound can migrate up to the cyclopentadienyl (Cp) site upon reaction with CO to achieve an overall exchange between the methyl and hydrogen (Cp) positions. In the presence of different metal-carbonyl complexes, easy dehydrogenation of the methyl group takes place under photochemical conditions to give methylidyne-bridged heterometallic clusters.

  DOI：

  10.1021/om800061z