[(CO)3Fe(μ-CH2)Te]2 | 164593-59-3

• 英文名称: [(CO)3Fe(μ-CH2)Te]2
• CAS: 164593-59-3
• 化学式: C₈H₄Fe₂O₆Te₂
• 分子量: 563.01
• InChiKey: BLAZYMNSNNQWNX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  重氮甲烷 、 Fe2(CO)6(μ-STe) 以 乙醚 为溶剂， 以4.1%的产率得到[(CO)3Fe(μ-CH2)Te]2
  参考文献：
  名称：

  Insertion of methylene group into FeTe bond: synthesis and characterization of {(CO)3Fe(μ-CH2)Te}2

  摘要：

  A novel methylene insertion product is reported. The new compound {(CO)(3)Fe(mu-CH2)Te}(2) has been isolated from the reaction of the mixed-chalcogenide compound Fe-2(CO)(6)(mu-STe) with diazomethane. It has been characterized by IR, H-1, C-13 and Te-125 NMR spectroscopy. Its structure has been determined by single-crystal X-ray diffraction methods: monoclinic; space group, P2(1)/c; a = 6.743(2), b = 10.996(2), c = 18.007(2) Angstrom, beta = 96.60(2)degrees; V = 1326.3(2) Angstrom(3); Z = 4; F(000) = 1024; Mo K alpha radiation (graphite monochromated); mu = 6.53 mm(-1); T = 293 K; D-c = 2.86 g cm(-3); R = 0.065 (R(w) = 0.064).

  DOI：

  10.1016/0022-328x(94)05353-d