(cyclopentadienyl)(CO)(PPh3)Fe(H2O)(+)*B(3,5-(CF3)2C6H3)4(-) | 207510-20-1

• 英文名称: (cyclopentadienyl)(CO)(PPh3)Fe(H2O)(+)*B(3,5-(CF3)2C6H3)4(-)
• CAS: 207510-20-1
• 化学式: C₂₄H₂₂FeO₂P*C₃₂H₁₂BF₂₄
• 分子量: 1292.48
• InChiKey: NPBWTNAYKXXTJQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex 、 三乙基硅烷 、 (cyclopentadienyl)(CO)(PPh3)Fe(CH3) 以 二氯甲烷-D2 为溶剂， 生成 (cyclopentadienyl)(CO)(PPh3)Fe(HSiEt3)(+)*B(3,5-(CF3)2C6H3)4(-) 、 (cyclopentadienyl)(CO)(PPh3)Fe(H2O)(+)*B(3,5-(CF3)2C6H3)4(-)
  参考文献：
  名称：

  Catalytic silane alcoholysis based on the C5H5(CO)(PPh3)Fe+ moiety. NMR spectroscopic identification of key intermediates

  摘要：

  The Cp(CO)(PPh3)Fe+ fragment has been shown to catalyze silane alcoholysis in the presence of the non-coordinating counterion, B Ar'(4)-(Ar' = 3,5-(CF3)(2)C6H3). When ethanol is used, catalyst deactivation rapidly occurs. However, when phenol is utilized, catalytic activity continues until all of the phenol has been consumed. In each case, key intermediates in the catalytic cycle, including resting states, have been observed using low temperature NMR spectroscopy. The modes of catalyst deactivation when ethanol is used have also been determined. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s1381-1169(97)00205-7