| 163354-11-8

• CAS: 163354-11-8
• 化学式: C₁₀H₉ClN₄OPd
• 分子量: 343.081
• InChiKey: ULXSUAWXOFCJKO-JNXPPIHMSA-M

反应信息

• 作为产物：
  描述：

  palladium dichloride 、 lithium chloride 、 在 AcONa 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, X-ray structure and reactivity of cyclopalladated complexes of hydrazones of 1H-indole-3-carboxaldehyde

  摘要：

  By reaction of Li-2[PdCl4] with substituted hydrazones of 1H-indole-3-carboxaldehyde the corresponding cyclopalladated complexes have been isolated and characterized. Compound 1a [C11H10ClN3OPd] reacts with PPh(3) by halogen displacement giving the cationic complex 5 the X-ray structure of which has revealed metallation at position 4 of the indole hydrazone, which is terdentate forming a [5,6]-fused ring system.

  DOI：

  10.1016/0022-328x(94)05113-p