[chloro(α-pycolyl-p-chloroiminoisonitrosoacetophenonate)copper(II)] | 1093864-51-7

• 英文名称: [chloro(α-pycolyl-p-chloroiminoisonitrosoacetophenonate)copper(II)]
• CAS: 1093864-51-7
• 化学式: C₁₄H₁₁Cl₂CuN₃O
• 分子量: 371.713
• InChiKey: XDZXCAUGZRFISD-FOBSECJHSA-L

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 α-pycolylimino-p-chloroisonitrosoacetophenone hydrochloride 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以60%的产率得到[chloro(α-pycolyl-p-chloroiminoisonitrosoacetophenonate)copper(II)]
  参考文献：
  名称：

  Synthesis of iminooxime derivatives and investigation of their complexes

  摘要：

  Three novel ligands, a-pycolyliminoisonitrosoacetophenone ((LH)-H-1 center dot HCl), alpha-pycolylimino-p-methylisonitrosoacetophenone ((LH)-H-2 center dot HCl), and a-pycolylimino-p-chloroisonitrosoacetophenone (LH)-H-3, were synthesized. Their metal complexes with Co(II), Cu(II), and Ni(II) were prepared. The mononuclear complexes of these ligands with Co2+, Cu2+, and Ni2+ ions were obtained in ethanol. The structures of the ligands and their complexes were characterized by 1H NMR, IR spectroscopy, elemental analyses, and magnetic susceptibility.

  DOI：

  10.1134/s1070328407090102