| 210560-05-7

• CAS: 210560-05-7
• 化学式: C₂₅H₁₆F₃N₂O₆ReS
• 分子量: 715.68
• InChiKey: RDNOCHDAUZAFSM-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  [Re(CO)3(3,3′-trimethylene-2,2′-biquinoline)(p-substituted-py)]+ complexes. Preparation and characterization

  摘要：

  A series of new rhenium(I) complexes of the type [Re(CO)(3)(3,3'-trimethylene-2,2'-biquinoline) (L)](CF3SO3)(n), (L = CF3 SO3- pyridine (py) or para-substituted pyridine like KO-py, ph-py or NC-py; n = 0 or 1) were prepared and characterized by FTIR, H-1 NMR, and UV-vis spectroscopies and by cyclic voltammetry. The pseudo-octahedral facial configuration of these compounds was established by FTIR. The differences found in the spectroscopical and electrochemical results were associated to the effect of the para position substituent of the L pyridine ligand. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00004-7