| 850661-59-5

• CAS: 850661-59-5
• 化学式: CH₂Cl₂*C₄₄H₃₅Au₂NP₂S
• 分子量: 1150.65
• InChiKey: PFFLVZIBIJBVEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三苯基膦氯金 、 苯基腈乙基硫醚 在 KOH 作用下， 以 甲醇 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  Understanding gold chemistry through relativity

  摘要：

  Gold chemistry is briefly reviewed indicating areas where a consideration of relativistic effects has led to major advances in the understanding of the special role of gold among the elements in the periodic table. On this basis, the unique properties of gold atoms and clusters, bulk gold and its surface, molecular and supramolecular compounds of gold, with aurophilic interactions, can be qualitatively rationalized or even quantitatively reproduced. A few complementary illustrative examples are given, where aurophilic bonding is instrumental in promoting auration of weakly acidic hydrocarbons XYCH2 to give dimetallated compounds XYC(AuL)(2), the structures of which show intimate interactions in the triangular CAu2 unit. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.chemphys.2004.09.023