dichloro(phthalocyanine(3-))antimony(V) | 159542-55-9

• 英文名称: dichloro(phthalocyanine(3-))antimony(V)
• CAS: 159542-55-9
• 化学式: C₃₂H₁₆Cl₂N₈Sb
• 分子量: 705.189
• InChiKey: YEZRDSBUPAOVDB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  dichloro(phthalocyaninato)antimony(V) tetrachloroantimonate(III) 在 银 作用下， 以 二氯甲烷 为溶剂， 以54%的产率得到dichloro(phthalocyanine(3-))antimony(V)
  参考文献：
  名称：

  Preparation of phthalocyanine(3−) species as bulk material by reduction of the dichloro(phthalocyaninato)antimony(V) complex cation

  摘要：

  By reduction of dichloro(phthalocyaninato)antimony(V) complex, [Sb(pc)Cl-2](+) (pc(2-) = phthalocyaninate, C32H16N82-), its pc(3-) species has been prepared as bulk material using elemental silver as the electron donor. One electron reduction of [Sb(pc)Cl,]+ proceeded without any side reaction. The obtained pc3- species has been characterized by its ESR, electronic absorption, infra-red, and mass spectra. The electronic absorption spectrum of the [Sb(pe(3-.))Cl-2] species was identical with that of the known spectro-electrochemically studied [Sb(pc(3-.))Cl-2]. The first infra-red spectrum of the pc(3-) species of metallophthalocyanine is reported and indicates that the structural change upon the reduction is insignificant. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.02.032